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Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film

Received: 11 March 2017     Accepted: 23 March 2017     Published: 24 April 2017
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Abstract

Quantum-chemical calculations using the Density Functional Theory (DFT) approach for structural analysis of a new azo benzene derivative: Sodium 6-amino-5-hydroxy-3-((E)-(2-methoxy-4-((E)-(4-sulfonatophenyl)diazenyl)phenyl)diazenyl)naphthalene-2-sulfonate (A) (trans isomer) was designed using B3LYP method with 6-311++G** basis set. The electronic absorption spectrum of the A in water solution was calculated using TDB3LYP/6-311++G** method. The excitation energies, electronic transitions and oscillator strengths for studied structure have also been calculated. On the basis of calculations a new dichroic azobenzene dye A was synthesized. The experimental UV-Vis, FT-IR and 1H NMR spectra of the title molecule were presented. On the basis of polyvinyl alcohol (PVA) and the dichroic synthesized azobenzene dye A thermostable polarizing film absorbing in the seen region of the spectrum (λmax = 550nm) with Polarization Efficiency (PE) in the absorption maximum (λmax = 92%) and Stretching Degree (Rs) = 3.0 was developed. The experimental spectral-polarization parameters of stretched colored PVA-films were measured. During the work it was established that oriented PVA-films is phenomenon of anisotropy of thermal conductivity). Thermal conductivity in a direction of orientation (λ) is higher than in a direction perpendicular orientations (λ).

Published in American Journal of Materials Synthesis and Processing (Volume 2, Issue 2)
DOI 10.11648/j.ajmsp.20170202.11
Page(s) 17-23
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Polarizer Film, Dichroic Dye, Thermal Conductivity, Polarization Efficiency

References
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    Siyamak Shahab, Liudmila Filippovich, Masoome Sheikhi, Hooriye Yahyaei, Maria Aharodnikova, et al. (2017). Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film. American Journal of Materials Synthesis and Processing, 2(2), 17-23. https://doi.org/10.11648/j.ajmsp.20170202.11

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    ACS Style

    Siyamak Shahab; Liudmila Filippovich; Masoome Sheikhi; Hooriye Yahyaei; Maria Aharodnikova, et al. Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film. Am. J. Mater. Synth. Process. 2017, 2(2), 17-23. doi: 10.11648/j.ajmsp.20170202.11

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    AMA Style

    Siyamak Shahab, Liudmila Filippovich, Masoome Sheikhi, Hooriye Yahyaei, Maria Aharodnikova, et al. Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film. Am J Mater Synth Process. 2017;2(2):17-23. doi: 10.11648/j.ajmsp.20170202.11

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  • @article{10.11648/j.ajmsp.20170202.11,
      author = {Siyamak Shahab and Liudmila Filippovich and Masoome Sheikhi and Hooriye Yahyaei and Maria Aharodnikova and Rakesh Kumar and Mehrnoosh Khaleghian},
      title = {Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film},
      journal = {American Journal of Materials Synthesis and Processing},
      volume = {2},
      number = {2},
      pages = {17-23},
      doi = {10.11648/j.ajmsp.20170202.11},
      url = {https://doi.org/10.11648/j.ajmsp.20170202.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajmsp.20170202.11},
      abstract = {Quantum-chemical calculations using the Density Functional Theory (DFT) approach for structural analysis of a new azo benzene derivative: Sodium 6-amino-5-hydroxy-3-((E)-(2-methoxy-4-((E)-(4-sulfonatophenyl)diazenyl)phenyl)diazenyl)naphthalene-2-sulfonate (A) (trans isomer) was designed using B3LYP method with 6-311++G** basis set. The electronic absorption spectrum of the A in water solution was calculated using TDB3LYP/6-311++G** method. The excitation energies, electronic transitions and oscillator strengths for studied structure have also been calculated. On the basis of calculations a new dichroic azobenzene dye A was synthesized. The experimental UV-Vis, FT-IR and 1H NMR spectra of the title molecule were presented. On the basis of polyvinyl alcohol (PVA) and the dichroic synthesized azobenzene dye A thermostable polarizing film absorbing in the seen region of the spectrum (λmax = 550nm) with Polarization Efficiency (PE) in the absorption maximum (λmax = 92%) and Stretching Degree (Rs) = 3.0 was developed. The experimental spectral-polarization parameters of stretched colored PVA-films were measured. During the work it was established that oriented PVA-films is phenomenon of anisotropy of thermal conductivity (λ‖/λ⊥). Thermal conductivity in a direction of orientation (λ‖) is higher than in a direction perpendicular orientations (λ⊥).},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - Spectroscopic (Polarization, ExcitedState, FT-IR, UV/Vis and 1H NMR) and Thermophysical Investigations of New Synthesized Azo Dye and Its Application in Polarizing Film
    AU  - Siyamak Shahab
    AU  - Liudmila Filippovich
    AU  - Masoome Sheikhi
    AU  - Hooriye Yahyaei
    AU  - Maria Aharodnikova
    AU  - Rakesh Kumar
    AU  - Mehrnoosh Khaleghian
    Y1  - 2017/04/24
    PY  - 2017
    N1  - https://doi.org/10.11648/j.ajmsp.20170202.11
    DO  - 10.11648/j.ajmsp.20170202.11
    T2  - American Journal of Materials Synthesis and Processing
    JF  - American Journal of Materials Synthesis and Processing
    JO  - American Journal of Materials Synthesis and Processing
    SP  - 17
    EP  - 23
    PB  - Science Publishing Group
    SN  - 2575-1530
    UR  - https://doi.org/10.11648/j.ajmsp.20170202.11
    AB  - Quantum-chemical calculations using the Density Functional Theory (DFT) approach for structural analysis of a new azo benzene derivative: Sodium 6-amino-5-hydroxy-3-((E)-(2-methoxy-4-((E)-(4-sulfonatophenyl)diazenyl)phenyl)diazenyl)naphthalene-2-sulfonate (A) (trans isomer) was designed using B3LYP method with 6-311++G** basis set. The electronic absorption spectrum of the A in water solution was calculated using TDB3LYP/6-311++G** method. The excitation energies, electronic transitions and oscillator strengths for studied structure have also been calculated. On the basis of calculations a new dichroic azobenzene dye A was synthesized. The experimental UV-Vis, FT-IR and 1H NMR spectra of the title molecule were presented. On the basis of polyvinyl alcohol (PVA) and the dichroic synthesized azobenzene dye A thermostable polarizing film absorbing in the seen region of the spectrum (λmax = 550nm) with Polarization Efficiency (PE) in the absorption maximum (λmax = 92%) and Stretching Degree (Rs) = 3.0 was developed. The experimental spectral-polarization parameters of stretched colored PVA-films were measured. During the work it was established that oriented PVA-films is phenomenon of anisotropy of thermal conductivity (λ‖/λ⊥). Thermal conductivity in a direction of orientation (λ‖) is higher than in a direction perpendicular orientations (λ⊥).
    VL  - 2
    IS  - 2
    ER  - 

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Author Information
  • Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus

  • Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus

  • Young Researchers and Elite Club, Gorgan Branch, Islamic Azad University, Gorgan, Iran

  • Department of Chemistry, Zanjan Branch, Islamic Azad University, Zanjan, Iran

  • Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, Minsk, Belarus

  • Department of Applied Sciences, CTIT, CT Group of Institutions, Jalandhar (Punjab), India

  • Department of Chemistry, Islamshahr Branch, Islamic Azad University, Islamshahr, Iran

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